The 48-year-old Good Wife star shared her excitement for the couple Sunday at a Variety and Women in Film's Emmys party.
"I'm thrilled!" Margulies told E! News at Gracias Madre in West Hollywood where the party took place. "She's a great girl."
Like all of Clooney's friends, Margulies refused to elaborate on any details she might be privy to on the upcoming Italian wedding.
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"George has always loved Como, he finds it very peaceful and relaxing and now Amal has fallen in love with the area as well," a source told E! News last week. "They want to start their married life there with the beautiful lake as a backdrop."
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If E!'s source is to be believed, it's unlikely Margulies, who will attend tonight's Emmys with her ninth nomination, will be an invitee at the wedding.
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"This is not going to be a huge Hollywood wedding with Julia Roberts and Sandra Bullock flying in to Italy for a week," said the source. "George and Amal don't want a media circus with paparazzi helicopters flying overhead and motorbikes chasing after them as they all arrive at the airport in Milan from Los Angeles. They want the wedding to be intimate with quiet but happy and fun dinners and lunches after they've said short but meaningful, hand-written vows in front of their loved ones."